Code of Federal Regulations Title 40. Protection of Environment 40 CFR Pt. 63, Subpt. UUUUU, Tbl. 5 Table 5 to Subpart UUUUU of Part 63—Performance Testing Requirements

1. Filterable Particulate matter (PM)

Emissions Testing

a. Select sampling ports location and the number of traverse points

Method 1 at appendix A-1 to part 60 of this chapter.

b. Determine velocity and volumetric flow-rate of the stack gas

Method 2, 2A, 2C, 2F, 2G or 2H at appendix A-1 or A-2 to part 60 of this chapter.

c. Determine oxygen and carbon dioxide concentrations of the stack gas

Method 3A or 3B at appendix A-2 to part 60 of this chapter, or ANSI/ASME PTC 19.10-1981.³

d. Measure the moisture content of the stack gas

Method 4 at appendix A-3 to part 60 of this chapter.

e. Measure the filterable PM concentration

Methods 5 and 5I at appendix A-3 to part 60 of this chapter.

For positive pressure fabric filters, Method 5D at appendix A-3 to part 60 of this chapter for filterable PM emissions.

Note that the Method 5 or 5I front half temperature shall be 160° ±14 °C (320° ±25 °F).

f. Convert emissions concentration to lb/MMBtu or lb/MWh emissions rates

Method 19 F-factor methodology at appendix A-7 to part 60 of this chapter, or calculate using mass emissions rate and gross output data (see § 63.10007(e)).

OR

OR

PM CEMS

a. Install, certify, operate, and maintain the PM CEMS

Performance Specification 11 at appendix B to part 60 of this chapter and Procedure 2 at appendix F to part 60 of this chapter.

b. Install, certify, operate, and maintain the diluent gas, flow rate, and/or moisture monitoring systems

Part 75 of this chapter and § 63.10010(a), (b), (c), and (d).

c. Convert hourly emissions concentrations to 30 boiler operating day rolling average lb/MMBtu or lb/MWh emissions rates

Method 19 F-factor methodology at appendix A-7 to part 60 of this chapter, or calculate using mass emissions rate and gross output data (see § 63.10007(e)).

2. Total or individual non-Hg HAP metals

Emissions Testing

a. Select sampling ports location and the number of traverse points

Method 1 at appendix A-1 to part 60 of this chapter.

b. Determine velocity and volumetric flow-rate of the stack gas

Method 2, 2A, 2C, 2F, 2G or 2H at appendix A-1 or A-2 to part 60 of this chapter.

c. Determine oxygen and carbon dioxide concentrations of the stack gas

Method 3A or 3B at appendix A-2 to part 60 of this chapter, or ANSI/ASME PTC 19.10-1981.³

d. Measure the moisture content of the stack gas

Method 4 at appendix A-3 to part 60 of this chapter.

e. Measure the HAP metals emissions concentrations and determine each individual HAP metals emissions concentration, as well as the total filterable HAP metals emissions concentration and total HAP metals emissions concentration

Method 29 at appendix A-8 to part 60 of this chapter. For liquid oil-fired units, Hg is included in HAP metals and you may use Method 29, Method 30B at appendix A-8 to part 60 of this chapter; for Method 29, you must report the front half and back half results separately. When using Method 29, report metals matrix spike and recovery levels.

f. Convert emissions concentrations (individual HAP metals, total filterable HAP metals, and total HAP metals) to lb/MMBtu or lb/MWh emissions rates

Method 19 F-factor methodology at appendix A-7 to part 60 of this chapter, or calculate using mass emissions rate and gross output data (see § 63.10007(e)).

3. Hydrogen chloride (HCl) and hydrogen fluoride (HF)

Emissions Testing

a. Select sampling ports location and the number of traverse points

Method 1 at appendix A-1 to part 60 of this chapter.

b. Determine velocity and volumetric flow-rate of the stack gas

Method 2, 2A, 2C, 2F, 2G or 2H at appendix A-1 or A-2 to part 60 of this chapter.

c. Determine oxygen and carbon dioxide concentrations of the stack gas

Method 3A or 3B at appendix A-2 to part 60 of this chapter, or ANSI/ASME PTC 19.10-1981.³

d. Measure the moisture content of the stack gas

Method 4 at appendix A-3 to part 60 of this chapter.

e. Measure the HCl and HF emissions concentrations

Method 26 or Method 26A at appendix A-8 to part 60 of this chapter or Method 320 at appendix A to part 63 of this chapter or ASTM D6348-03 ³ with

․

(1) the following conditions when using ASTM D6348-03:

․

(A) The test plan preparation and implementation in the Annexes to ASTM D6348-03, Sections A1 through A8 are mandatory;

․

(B) For ASTM D6348-03 Annex A5 (Analyte Spiking Technique), the percent (%) R must be determined for each target analyte (see Equation A5.5);

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(C) For the ASTM D6348-03 test data to be acceptable for a target analyte, ^{must be 70% ≥R ≤130%; and}

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(2) spiking levels nominally no greater than two times the level corresponding to the applicable emission limit.

․

Method 26A must be used if there are entrained water droplets in the exhaust stream.

f. Convert emissions concentration to lb/MMBtu or lb/MWh emissions rates

Method 19 F-factor methodology at appendix A-7 to part 60 of this chapter, or calculate using mass emissions rate and gross output data (see § 63.10007(e)).

OR

OR

HCl and/or HF CEMS

a. Install, certify, operate, and maintain the HCl or HF CEMS

Appendix B of this subpart.

b. Install, certify, operate, and maintain the diluent gas, flow rate, and/or moisture monitoring systems

Part 75 of this chapter and § 63.10010(a), (b), (c), and (d).

c. Convert hourly emissions concentrations to 30 boiler operating day rolling average lb/MMBtu or lb/MWh emissions rates

Method 19 F-factor methodology at appendix A-7 to part 60 of this chapter, or calculate using mass emissions rate and gross output data (see § 63.10007(e)).

4. Mercury (Hg)

Emissions Testing

a. Select sampling ports location and the number of traverse points

Method 1 at appendix A-1 to part 60 of this chapter or Method 30B at Appendix A-8 for Method 30B point selection.

b. Determine velocity and volumetric flow-rate of the stack gas

Method 2, 2A, 2C, 2F, 2G or 2H at appendix A-1 or A-2 to part 60 of this chapter.

c. Determine oxygen and carbon dioxide concentrations of the stack gas

Method 3A or 3B at appendix A-1 to part 60 of this chapter, or ANSI/ASME PTC 19.10-1981.³

d. Measure the moisture content of the stack gas

Method 4 at appendix A-3 to part 60 of this chapter.

e. Measure the Hg emission concentration

Method 30B at appendix A-8 to part 60 of this chapter, ASTM D6784,³ or Method 29 at appendix A-8 to part 60 of this chapter; for Method 29, you must report the front half and back half results separately.

f. Convert emissions concentration to lb/TBtu or lb/GWh emission rates

Method 19 F-factor methodology at appendix A-7 to part 60 of this chapter, or calculate using mass emissions rate and gross output data (see § 63.10007(e)).

OR

OR

Hg CEMS

a. Install, certify, operate, and maintain the CEMS

Sections 3.2.1 and 5.1 of appendix A of this subpart.

b. Install, certify, operate, and maintain the diluent gas, flow rate, and/or moisture monitoring systems

Part 75 of this chapter and § 63.10010(a), (b), (c), and (d).

c. Convert hourly emissions concentrations to 30 boiler operating day rolling average lb/TBtu or lb/GWh emissions rates

Section 6 of appendix A to this subpart.

OR

OR

Sorbent trap monitoring system

a. Install, certify, operate, and maintain the sorbent trap monitoring system

Sections 3.2.2 and 5.2 of appendix A to this subpart.

b. Install, operate, and maintain the diluent gas, flow rate, and/or moisture monitoring systems

Part 75 of this chapter and § 63.10010(a), (b), (c), and (d).

c. Convert emissions concentrations to 30 boiler operating day rolling average lb/TBtu or lb/GWh emissions rates

Section 6 of appendix A to this subpart.

OR

OR

LEE testing

a. Select sampling ports location and the number of traverse points

Single point located at the 10% centroidal area of the duct at a port location per Method 1 at appendix A-1 to part 60 of this chapter or Method 30B at Appendix A-8 for Method 30B point selection.

b. Determine velocity and volumetric flow-rate of the stack gas

Method 2, 2A, 2C, 2F, 2G, or 2H at appendix A-1 or A-2 to part 60 of this chapter or flow monitoring system certified per appendix A of this subpart.

c. Determine oxygen and carbon dioxide concentrations of the stack gas

Method 3A or 3B at appendix A-1 to part 60 of this chapter, or ANSI/ASME PTC 19.10-1981,³ or diluent gas monitoring systems certified according to part 75 of this chapter.

d. Measure the moisture content of the stack gas

Method 4 at appendix A-3 to part 60 of this chapter, or moisture monitoring systems certified according to part 75 of this chapter.

e. Measure the Hg emission concentration

Method 30B at appendix A-8 to part 60 of this chapter; perform a 30 operating day test, with a maximum of 10 operating days per run (i.e., per pair of sorbent traps) or sorbent trap monitoring system or Hg CEMS certified per appendix A of this subpart.

f. Convert emissions concentrations from the LEE test to lb/TBtu or lb/GWh emissions rates

Method 19 F-factor methodology at appendix A-7 to part 60 of this chapter, or calculate using mass emissions rate and gross output data (see § 63.10007(e)).

g. Convert average lb/TBtu or lb/GWh Hg emission rate to lb/year, if you are attempting to meet the 29.0 lb/year threshold

Potential maximum annual heat input in TBtu or potential maximum electricity generated in GWh.

5. Sulfur dioxide (SO₂)

SO₂ CEMS

a. Install, certify, operate, and maintain the CEMS

Part 75 of this chapter and § 63.10010(a) and (f).

b. Install, operate, and maintain the diluent gas, flow rate, and/or moisture monitoring systems

Part 75 of this chapter and § 63.10010(a), (b), (c), and (d).

c. Convert hourly emissions concentrations to 30 boiler operating day rolling average lb/MMBtu or lb/MWh emissions rates

Method 19 F-factor methodology at appendix A-7 to part 60 of this chapter, or calculate using mass emissions rate and gross output data (see § 63.10007(e)).